Also, it is known for low Equivalent Series Resistance (ESR), that means, only a small amount of energy is lost while its charging/discharging even at high current. This is attributed to its high‐power density, superior performance, and extended maintenance‐free lifetime. In this regard, supercapacitors have evolved as an efficient energy storage solution and hence successfully employed in several applications. This has led to high level awareness of proper energy storage and management. The dependence on renewable energy to solve the major energy issues related to global warming and shortage of energy resources is increasing drastically. This review presents the potential of LIBs participating in grid service via pulsed operation and may provide forward-looking guidance for the community. The hardware that supports bidirectional pulse is also introduced. The pulsed operation with appropriate parameters can provide superior effects for LIBs even under high-power charging and low-temperature operation. Specific attention is paid to the fundamental mechanisms of pulsed operation on the stability of electric power system and micro-evolution in cells. This review therefore highlights pulsed operation on LIBs for future grids, covering mechanisms, effects, and supporting hardware. LIB deployment is also expected to reach 20 TWh from a vehicle-to-grid application by 2030. Operating lithium-ion batteries (LIBs) under pulsed operation can effectively address these issues, owing to LIBs providing the rapid response and high energy density required. The large-scale utilization of renewable energy sources can lead to grid instability due to dynamic fluctuations in generation and load.
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